Arrange the following substances in chronological order of their first synthesis in lab:

1. Black gold
2. Fullerene
3. Graphene
4. Kevlar

Select correct answer from the codes given below:
Codes:

A) 1 2 3 4

B) 4 2 3 1

C) 2 4 3 1

D) 4 1 2 3

This MCQ is part of the UP PSC Previous Year Questions (PYQs) series, focusing on UPPSC Prelims 2019 (GS Paper I)